The high theoretical capacity (∼2000 mAh g −1 ) of silicon suboxide (SiO x , with 1 < x < 2) can solve the energy density issue of the graphite anode in Li-ion batteries. In addition, it has an advantage in terms of volume expansion or side reactions compared to pure Si or Li metals, which are considered as nextgeneration anode materials. However, the loading content of SiO x is limited in commercial anodes because of its low cycle stability and initial coulombic efficiency. In this study, a nitrogen-doped carbon layer with Cu beads (N−C/Cu) derived from copper phthalocyanine (CuPc) is applied to a SiO x electrode to improve its electrochemical performance. The SiO x electrode is simultaneously coated with a Cu-and N-doped carbon layer using CuPc. N−C/Cu synergistically enhances the electric conductivity of the electrode, thus improving its electrochemical performance. The SiO x /N−C/Cu composite has better cyclability and higher capacity (1095.5 mAh g −1 ) than the uncoated electrode, even after 200 cycles in the 0.5 C condition. In full-cell cycling with NCM811 cathodes, the SiO x (60 wt % of SiO x , with a n/p ratio of 1.1) and graphite-mixed (7.8 wt % of SiO x , with a n/p ratio of 1.1) anodes also show improved electrochemical performances in the same conditions.