Novel SnS2-nanosheet anodes for lithium-ion batteries

Kim, Tae‐Joon; Kim, Chunjoong; Son, Dongyeon; Choi, Myungsuk; Park, Byungwoo

doi:10.1016/j.jpowsour.2007.02.040

Cited by 318 publications

(259 citation statements)

References 24 publications

Supporting

Mentioning

252

Contrasting

Order By: Relevance

“…After the emergence of novel 2D materials and improved production methods such as chemical vapor deposition and chemical and mechanical exfoliation, thinner structures of SnS 2 were synthesized for different applications. For example, a few nanometers thick hexagonal SnS 2 was used for lithium storage in battery applications [35][36][37][38]. To enhance the electrochemical performance, composite forms of SnS 2 with graphene were examined [39][40][41][42][43].…”

Section: Introductionmentioning

confidence: 99%

BilayerSnS2: Tunable stacking sequence by charging and loading pressure

et al. 2016

View full text Add to dashboard Cite

Employing density functional theory-based methods, we investigate monolayer and bilayer structures of hexagonal SnS 2 , which is a recently synthesized monolayer metal dichalcogenide. Comparison of the 1H and 1T phases of monolayer SnS 2 confirms the ground state to be the 1T phase. In its bilayer structure we examine different stacking configurations of the two layers. It is found that the interlayer coupling in bilayer SnS 2 is weaker than that of typical transition-metal dichalcogenides so that alternative stacking orders have similar structural parameters and they are separated with low energy barriers. A possible signature of the stacking order in the SnS 2 bilayer has been sought in the calculated absorbance and reflectivity spectra. We also study the effects of the external electric field, charging, and loading pressure on the characteristic properties of bilayer SnS 2 . It is found that (i) the electric field increases the coupling between the layers at its preferred stacking order, so the barrier height increases, (ii) the bang gap value can be tuned by the external E field and under sufficient E field, the bilayer SnS 2 can become a semimetal, (iii) the most favorable stacking order can be switched by charging, and (iv) a loading pressure exceeding 3 GPa changes the stacking order. The E-field tunable band gap and easily tunable stacking sequence of SnS 2 layers make this 2D crystal structure a good candidate for field effect transistor and nanoscale lubricant applications.

show abstract

Section: Introductionmentioning

confidence: 99%

BilayerSnS2: Tunable stacking sequence by charging and loading pressure

et al. 2016

View full text Add to dashboard Cite

show abstract

“…Typically, four reduction peaks can be found in cathodic scans from the CV curves. The reduction peak at 1.83 V (vs. Li/Li + ) is known to arise from the lithium intercalation into SnS 2 without a phase decomposition (Equation (1)) [29,30]. The reduction peaks at 1.62 and 1.19 V (vs. Li/Li + ) in the first cathodic sweep could be attributed to the decomposition of SnS 2 into metallic tin and the formation of Li 2 S (Equation (2)), which may occur in three steps [30], as well as the formation of a solid electrolyte interface (SEI) [11,31].…”

Section: Electrochemical Performancementioning

confidence: 99%

“…The reduction peak at 1.83 V (vs. Li/Li + ) is known to arise from the lithium intercalation into SnS 2 without a phase decomposition (Equation (1)) [29,30]. The reduction peaks at 1.62 and 1.19 V (vs. Li/Li + ) in the first cathodic sweep could be attributed to the decomposition of SnS 2 into metallic tin and the formation of Li 2 S (Equation (2)), which may occur in three steps [30], as well as the formation of a solid electrolyte interface (SEI) [11,31]. The peak at 0.22 V (vs. Li/Li + ) in the first anodic scan corresponds to the reversible formation of Li x Sn alloy (Equation (3)) and the oxidation peak at 0.50 V (vs. Li/Li + ) in the first anodic scan possibly originates from the delithiation reaction of Li x Sn alloy (Equation (3)).…”

Section: Electrochemical Performancementioning

confidence: 99%

“…The peak at 0.22 V (vs. Li/Li + ) in the first anodic scan corresponds to the reversible formation of Li x Sn alloy (Equation (3)) and the oxidation peak at 0.50 V (vs. Li/Li + ) in the first anodic scan possibly originates from the delithiation reaction of Li x Sn alloy (Equation (3)). The above kinetics can be described by the electro-chemical conversion reactions [30,32] x x SnS + Li + e Li SnS , …”

Section: Electrochemical Performancementioning

confidence: 99%

See 1 more Smart Citation

Rational synthesis of SnS2@C hollow microspheres with superior stability for lithium-ion batteries

Yang

Ding

et al. 2017

Sci. China Mater.

View full text Add to dashboard Cite

“…SnS 2 is an n-type semiconductor with a bandgap of 2.18-2.44 eV [8,9], and has good stability in acid and neutral aqueous solutions as well as certain oxidative and thermal stability in air, which makes it become a promising visible light-sensitive photocatalyst [10]. In addition, because of its intriguing electrical, optical and gas sensing properties, SnS 2 has been chosen as a candidate material in solar cells and opto-electronic devices, electrode for lithium-ion batteries, pigment and gas sensor [11][12][13].…”

Section: Introductionmentioning

confidence: 99%

Preparation, Characterization and Application of Carbon Nanotubes Wrapped Nanoflake-like SnS2 Composite

Li¹,

Qin²,

Yang³

2012

Proceedings of the 2nd International Conference on Electronic and Mechanical Engineering and Information Technology (2012)

View full text Add to dashboard Cite

Abstract.A novel multiwall carbon nanotubes wrapped nanoflake-like SnS 2 (MWCNTs-SnS 2 ) composite was designed by simply mixing carbon nanotubes with nanoflake-like SnS 2 . The fabricated MWCNTs-SnS 2 composite material was characterized using scan electron microscopy and transmission electron microscopy. The MWCNTs-SnS 2 was used to modify glassy carbon electrode to examine the electrocatalysis of hydrogen peroxide and oxygen. Moreover, direct electrochemistry of glucose oxides immobilized on MWCNTs-SnS 2 modified electrode was investigated. This MWCNTs-SnS 2 composite provided a promising approach to fabricate electrochemical sensor.

show abstract

Novel SnS2-nanosheet anodes for lithium-ion batteries

Cited by 318 publications

References 24 publications

BilayerSnS2: Tunable stacking sequence by charging and loading pressure

BilayerSnS2: Tunable stacking sequence by charging and loading pressure

Rational synthesis of SnS2@C hollow microspheres with superior stability for lithium-ion batteries

Preparation, Characterization and Application of Carbon Nanotubes Wrapped Nanoflake-like SnS2 Composite

Contact Info

Product

Resources

About