Novel ternary AgIICoIIIF5 fluoride: synthesis, structure and magnetic characteristics
Daniel Jezierski,
Zoran Mazej,
Wojciech Grochala
Abstract:As Ag2+ is such a powerful oxidizer, not many open-shell transition metal cations can resist its neighborhood. Here we introduce AgCoF5, a rare representative of the transition metal–Ag2+ fluoride family.
A new family of intergrowth structures containing strongly correlated antiferromagnetic layers of AgF2 is introduced. Charge reservoir layers allow to control the strain and magnetic properties, rendering them superior to oxocuprates(ii).
A new family of intergrowth structures containing strongly correlated antiferromagnetic layers of AgF2 is introduced. Charge reservoir layers allow to control the strain and magnetic properties, rendering them superior to oxocuprates(ii).
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