Output fluctuation and lower transmission efficiency under load and mutual inductance variation are hot concerned in the wireless charging system for power batteries. In this paper, a decoupled tracking strategy is proposed to realize constant voltage (CV) or current (CC) output and high transmission efficiency. The circuit model of series–series compensation network is built, and corresponding transmission characteristics can be derived. First, the load and mutual inductance value can be estimated by measuring the primary electrical information, including the inverter output voltage, current, and the phase error between them. Then load‐independent voltage or current output characteristics under coils misalignment can be maintained by tracking the optimal switching frequency of inverter part. In addition, the value of output voltage or current can be adjusted flexibly for different operation occasions by the employment of pulse‐width modulation. As a result, the load‐independent output characteristics realization and output adjustment can be decoupled. Based on only the primary measuring information, the CV/CC output can be maintained via the proposed hybrid control strategy when the coils misalignment and load variation happen, increasing the robustness of whole wireless power transfer (WPT) system. Furthermore, the soft switching of all power switches in the inverter part can be realized to reduce the switching loss. Compared with previous research, the proposed wireless charging system has a higher power density and a simplified control strategy. Finally, an experimental platform with 60‐V charging voltage and 3.6‐A charging current is built to verify the feasibility of the proposed sys‐tem and control method.