2015
DOI: 10.1021/acs.iecr.5b01932
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Novel Two-Step Process for the Production of Renewable Aromatic Hydrocarbons from Triacylglycerides

Abstract: A two-step process was developed for the production of aromatic hydrocarbons from triglyceride (TG) oils. In the first reaction step, TG (soybean) oil was noncatalytically cracked and purified by distillation to produce an organic liquid product (OLP). The resulting OLP was then converted into aromatic compounds in a second reaction using a zeolite catalyst, HZSM-5. In this second reaction, three main factors were found to influence the yield of aromatic hydrocarbons: the SiO2:Al2O3 ratio in the HZSM-5, the re… Show more

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Cited by 25 publications
(15 citation statements)
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“…This may explain the shift of the aromatic homology profile from C 7 –C 8 for smaller‐size alkene feedstocks to C 8 –C 10 for 1‐tetradecene. Corroborating this hypothesis, C 9 –C 11 aromatics were found to be predominant when the carboxylic acids of triacylglycerols, which are also large molecules, were treated with zeolites under similar conditions (Benson et al, ; Fegade et al, ).…”
Section: Resultsmentioning
confidence: 93%
“…This may explain the shift of the aromatic homology profile from C 7 –C 8 for smaller‐size alkene feedstocks to C 8 –C 10 for 1‐tetradecene. Corroborating this hypothesis, C 9 –C 11 aromatics were found to be predominant when the carboxylic acids of triacylglycerols, which are also large molecules, were treated with zeolites under similar conditions (Benson et al, ; Fegade et al, ).…”
Section: Resultsmentioning
confidence: 93%
“…Biomass‐derived polymers are attractive alternatives to those derived from petroleum as they offer a route to fully sustainable materials. Among the currently available biomass based polymers, those that bear renewably sourced aromatic units are rare, owing to the difficulty of acquiring aromatic monomers from biomass . Nevertheless, when aromatic ring structures are incorporated into a polymer, they grant desirable physical properties to the material .…”
Section: Introductionmentioning
confidence: 99%
“…The chemical reaction named as the Michael addition reaction was introduced in the year of 1884 by the research of Arthur Michael, inspired by the work of Conard and Kuthzeit 53 . Initially, the Michael addition was considered as the addition of an enolate ion into the β-carbon atom of an α,β-unsaturated carbonyl compound 53 .…”
Section: Michael Addition Reactionmentioning
confidence: 99%
“…The chemical reaction named as the Michael addition reaction was introduced in the year of 1884 by the research of Arthur Michael, inspired by the work of Conard and Kuthzeit 53 . Initially, the Michael addition was considered as the addition of an enolate ion into the β-carbon atom of an α,β-unsaturated carbonyl compound 53 . Over the years, the Michael addition is not confined to the addition of only carbanions, as variety of nucleophiles bearing heteroatoms like nitrogen, oxygen, sulphur, and phosphor proved suitable Michael donors (scheme 1.1).…”
Section: Michael Addition Reactionmentioning
confidence: 99%
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