“…Above all, to the best of our knowledge, mTPA–PPI is among the best NUV materials that have ever been reported, and exhibits a combination of a high-efficiency NUV EL, a narrow FWHM and a small y -value of CIE coordinate. 3d , 6 Key data of the mTPA–PPI-based device and other high-performance violet/NUV light-emitting devices with EL wavelengths below 410 nm are listed together in Table S5 † for the purpose of comparison. The superior device performances of mTPA–PPI could be ascribed to the following facts: (i) the meta -linkage of mTPA–PPI gives rise to a LE emission like PPI, which inherits high η PL and good colour-purity of the parent PPI; (ii) the introduction of a high-lying CT state promotes a RISC process to enhance η s in the mTPA–PPI device; (iii) the rising HOMO level facilitates easier hole injection in the mTPA–PPI layer due to the incorporation of TPA.…”