2010
DOI: 10.1016/j.inoche.2010.02.013
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Novel W(II) complexes for reversible addition-fragmentation chain transfer (RAFT) polymerizations

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Cited by 14 publications
(14 citation statements)
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“…[27] In parallel, Chen et al polymerized St and tert-butyl acrylate by using tungstenpentacarbonyl derivatives with benzyl and allyl as leaving R groups. [28] Our first results confirmed that these metallophosphorus-based compounds behave as efficient RAFT agents. It appeared that their efficiency was not altered by varying the nature of the metal center.…”
Section: Introductionsupporting
confidence: 68%
“…[27] In parallel, Chen et al polymerized St and tert-butyl acrylate by using tungstenpentacarbonyl derivatives with benzyl and allyl as leaving R groups. [28] Our first results confirmed that these metallophosphorus-based compounds behave as efficient RAFT agents. It appeared that their efficiency was not altered by varying the nature of the metal center.…”
Section: Introductionsupporting
confidence: 68%
“…The resonances were calibrated relative to the residual solvent resonances and were reported with positive values downfield from TMS. For all characterized compounds, the peak assignments in the 1 H and 13 C NMR spectra were based on COSY, HSQC, and HMBC 2D experiments. HRMS were obtained from dichloromethane solutions with a Xevo G2 Q TOF spectrometer by the electrospray or chemical ionization method.…”
Section: ■ Experimental Sectionmentioning
confidence: 99%
“…1 H (400 MHz, CDCl 3 ) δ: 7.36−7.18 (5H, m, Ph), 5.17 (1H, qd, 3 J HH = 7.1 Hz, 4 J HP = 1.8 Hz, CHCH 3 ), 1.65 (3H, dd, 3 J HH = 7.1 Hz, 5 J HP = 0.6 Hz, CHCH 3 ), 1.35 (9H, d, 3 J HP = 14.3 Hz, C(CH 3 ) 3 ), 1.27 (9H, d, 3 J HP = 14.3 Hz, C(CH 3 ) 3 ). 13 C{ 1 H} (125 MHz, CDCl 3 ) δ: 239.0 (d, 1 J CP = 45.2 Hz, C(S)S), 140.6 ( Ph C-CHCH 3 ), 128.5 ( Ph CH), 127.8 ( Ph CH), 127.7 ( Ph CH), 47.3 (d, 3 J CP = 1.6 Hz, CHCH 3 ), 37.17 (d, 1 J CP = 55.6 Hz, C(CH 3 ) 3 ), 37.15 (d, 1 J CP = 55.8 Hz, C(CH 3 ) 3 ), 27.17 (C(CH 3 ) 3 ), 27.09 (C(CH 3 ) 3 ), 20.2 (CHCH 3 ). 31 Alternative Synthetic Procedure for 6.…”
Section: ■ Experimental Sectionmentioning
confidence: 99%
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