Novel water‐soluble acryloylmorpholine copolymers: Synthesis, characterization, and metal ion binding properties

Rivas, Bernabé L.; Maureira, Antonio; Geckeler, Kurt E.

doi:10.1002/app.23163

Cited by 29 publications

(12 citation statements)

References 27 publications

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“…Other area of application is in the removal of metal ions from an aqueous waste which is an important field for environmental research. The metal binding properties of poly(2-acrylamido-2-methyl-1-propane sulphonic acid) (AMPS) were studied by the liquidphase polymer-based retention technique, under different experimental conditions [12]. This strong polyelectrolyte showed a high retention for di-and trivalent cations at all pH.…”

Section: Introductionmentioning

confidence: 99%

Self-assembly of physically crosslinked micelles of poly(2-acrylamido-2-methyl-1-propane sulphonic acid-co-isodecyl methacrylate)-copper(II) complexes

Miguel

Catalina

Peinado

2008

European Polymer Journal

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Section: Introductionmentioning

confidence: 99%

Self-assembly of physically crosslinked micelles of poly(2-acrylamido-2-methyl-1-propane sulphonic acid-co-isodecyl methacrylate)-copper(II) complexes

Miguel

Catalina

Peinado

2008

European Polymer Journal

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“…The stock 5 mg mL -1 polymer solution was prepared by dissolving an exact weighted sample of each polymer in deionized water Polydisperse substances. Poly(acryloyl morpholine-co-2-acrylamido-2-methyl-1-propane sulfonic acid) and poly[2-acrylamido-2-methyl-1-propane sulfonic acid-co-(3-acryloylamidopropyl) trimethylammonium nitrate) were synthesized by radical polymerization as previously described [15,16]. Molar masses for both polymers were determined means light scattering, using a Wyatt Dawn DSP-F photometer with a argon laser, and a interferometric refractometer Wyatt Optilab 903.…”

Section: Reagentsmentioning

confidence: 99%

Online Multi-Stage Membrane Filtration of Synthetic Polydispersed Water-Soluble Polymers With Uv Visible Absorption as a Mode for Their Detection

Rivas¹,

Shkinev

Dzherajan³

et al. 2010

J. Chil. Chem. Soc.

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This paper reports the application of online membrane filtration with UV visible absorption as a mode of polydispersed substances detection for poly(acryloyl morpholine-co-2-acrylamido-2-methyl-1-propane sulfonic acid), poly[2-acrylamido-2-methyl-1-propane sulfonic acid-co-(3-acryloylamidopropyl) trimethylammonium nitrate), and poly(vinyl alcohol-co-crotonic acid) 10 % of crotonic acid which can be used in medicine and technology. The mass balance in all the cases was not below 100 ± 7 %. The calibration curve are linear at l opt. 245, 230, and 220 nm in the interval 0.1-4.0 mg/mL, 0.2-3.0 mg/mL and 0.2-6.0 mg/mL, respectively.It was also used the combination of microfiltration, MF, and gel permeation chromatography, GPC to provide more complete information about the molecular weight distribution of the obtained fractions.

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“…The choice of this monomer combination was made with the aim to prepare a temperature responsive gel with good swelling capacity and mechanical stability. The poly(NIPAM) in the gel imparts temperature sensitivity (24), and poly(AM) imparts additional hydrophilicity and mechanical stability to the gels (25,26). These properties are important for using these gels as sorbents for the removal of dyes and metals from aqueous solution.…”

Section: Introductionmentioning

confidence: 98%

Network Structure and Congo Red Dye Removal Characteristics of New Temperature-Responsive Hydrogels

Deen

Lim

Mah

et al. 2014

Separation Science and Technology

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New temperature-responsive hydrogels containing various composition of N-acryloyl morpholine (AM) and N-isopropyl acrylamide (NIPAM) were prepared by free-radical solution polymerization using poly(ethyleneglycol) diacrylate (PEGDA) as the chemical crosslinker. The gels were responsive to changes in external temperature, and exhibited the volume phase transition phenomenon. The gels swelled extensively in water at 23 °C, with water-uptake of more than 90 % at swelling equilibrium. The influence of molecular heterogeneity of the gels in terms of comonomer and crosslinker composition on the swelling capacity and equilibrium water uptake was evaluated. The dye adsorption capacity of the gels at room temperature was studied using Congo red as a model dye. The gels displayed significant adsorption capacity of the dye, and the adsorption capacity was found to be dependent on the hydrophilic character of the gel.The characteristic adsorption parameters were determined using the Langmuir isotherm model.The value of equilibrium binding constant was below 1 which indicated favorable adsorption of dye by the hydrogels. The dye release behavior was studied below and above the volume phase transition temperature of the gels. The dye release from the gels was about 95 % at temperatures above the volume phase transition temperature of the gels. These gels can be used as reversible sorbents in the efficient removal of Congo red from waste water.A c c e p t e d M a n u s c r i p t 2 INTRODUCTION Hydrogels are cross-linked three-dimensional polymer networks that can absorb large amounts of water and remain insoluble. Depending on the nature of chemical units along the polymer chain, these materials can be made to respond to changes in certain external stimuli such as pH, temperature, ionic strength, illumination, and magnetic field (1-5), and are called stimuliresponsive, intelligent, smart, or environmentally sensitive polymers. The potential response to these stimuli is changes in phase, shape, volume or optical properties. Due to their excellent properties such as biocompatibility, elasticity, and water-uptake capacity, hydrogels have found applications in skin care products, targeted drug delivery systems, enzyme immobilizations, dye sorbents and chemical sensors (5-10). In many of these applications, the swelling property and strength of the hydrogel plays an important role which has been the subject of research interest in recent years.The development of new sorbents to remove organic or heavy metal pollutants from organic effluents produced in textile, paper, leather, and plastic industries represents an intensive and popular area of research. The main source of water and land pollution is by effluents from textile and leather industries. As a result of dying process, these industrial effluents are colored and contain synthetic organic dyes which are hazardous to the environment and biological activities in water bodies.These organic dyes are also mutagenic and carcinogenic in nature and hence very hazardous to human health...

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Novel water‐soluble acryloylmorpholine copolymers: Synthesis, characterization, and metal ion binding properties

Cited by 29 publications

References 27 publications

Self-assembly of physically crosslinked micelles of poly(2-acrylamido-2-methyl-1-propane sulphonic acid-co-isodecyl methacrylate)-copper(II) complexes

Self-assembly of physically crosslinked micelles of poly(2-acrylamido-2-methyl-1-propane sulphonic acid-co-isodecyl methacrylate)-copper(II) complexes

Online Multi-Stage Membrane Filtration of Synthetic Polydispersed Water-Soluble Polymers With Uv Visible Absorption as a Mode for Their Detection

Network Structure and Congo Red Dye Removal Characteristics of New Temperature-Responsive Hydrogels

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