“…Nevertheless, as the grain size decreases, the number of charge carriers decreases due to the continued electron loss to the grain boundaries. On the other hand, our previous study shows that the grain size of BZT decreases as the rare earth ions content increases [13,14] which indicates that Ho substituted BZT used in this work has the smallest grains; therefore, BHZT has the highest bulk resistance. Moreover, as the grain size decreases the area of the grain boundaries and electrode interface increases, and this leads to an increase in the grain boundaries-electrode resistance due to the increase of the spatial charge density.…”