Next-generation large-scale neutrino detectors, from Eos, at the 1 t scale, to Theia, at the 10 s-of-kt scale, will utilize differences in both the scintillation and Cherenkov light emission for different particle species to perform background rejection. This manuscript presents measurements of the scintillation light yield and emission time profile of water-based liquid scintillator samples in response to $$\alpha $$
α
radiation. These measurements are used as input to simulation models used to make predictions for future detectors. In particular, we present the timing-based particle identification achievable in generic water-based scintillator detectors at the 4 t, 1 kt, and 100 kt scales. We find that $$\alpha $$
α
/$$\beta $$
β
discrimination improves with increasing scintillation concentration and we identify better than 80% $$\alpha $$
α
rejection for 90% $$\beta $$
β
acceptance in 10% water-based liquid scintillator, at the 4 t scale.