Nuclear magnetic resonance in single‐crystal lead

Abstract

NMR-signals from an oriented lead single crystal were obtained a t 4.2 K for the [OOl] and [I101 direction parallel to the magnetic field. A spectrometer with a superconducting magnet and digital data acquisition was used. The orientation dependence of the second moments of the line was employed to determine the value of the pseudodipolar coupling constant B(rij) for the first two shells of nearest neighbours. Orientierungsabhlngigkeit der zweiten Momente der Linie wurde der Wert der pseudodipolaren Kopplungskonstanten B(rij) fur die nachsten und ubernachsten Nachbarn bestimmt.

Single-Crystal NMR Spectroscopy

“…Although 207 Pb NMR has been extensively used to study different lead-containing solids [108], to our knowledge there have only been few 207 Pb SC NMR studies in the past [109,110], until this has recently been brought up by Bräuniger and co-workers [48,[111][112][113]. In their combined 51 V and 207 Pb SC NMR study of Pb 5 (VO 4 ) 3 Cl [48], they observed the expected 207 Pb resonances originating from three magnetically inequivalent lead atoms in pos 6h and two in pos 4f.…”