Accurate atomic mass measurements of neutron-deficient and neutron-rich nuclides around the doubly-magic 208 Pb and of neutron-rich cesium isotopes were performed with the Penning trap mass spectrometer ISOLTRAP at ISOLDE/CERN. Pb,[190][191][192][193][194][195][196][197] 209,215,216 Bi, 203,205,229 Fr, and 214,229,230 Ra were determined. The obtained relative mass uncertainty in the range of 2 · 10 −7 to 2 · 10 −8 is not only required for safe identification of isomeric states but also allows mapping the detailed structure of the mass surface. A mass adjustment procedure was carried out and the results included into the Atomic Mass Evaluation. The resulting separation energies are discussed and the mass spectrometric and laser spectroscopic data are examined for possible correlations.