2023
DOI: 10.3390/polym15122721
|View full text |Cite
|
Sign up to set email alerts
|

Nucleophilic Aromatic Substitution of Pentafluorophenyl-Substituted Quinoline with a Functional Perylene: A Route to the Modification of Semiconducting Polymers

Abstract: A systematic study of the influence of the chemical substitution pattern of semiconducting polymers carrying side chain perylene diimide (PDI) groups is presented. Semiconducting polymers based on perflurophenyl quinoline (5FQ) were modified via a readily accessible nucleophilic substitution reaction. The perfluorophenyl group was studied as an electron-withdrawing reactive functionality on semiconducting polymers that can undergo fast nucleophilic aromatic substitution. A PDI molecule, functionalized with one… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1

Citation Types

0
1
0

Year Published

2023
2023
2023
2023

Publication Types

Select...
1
1

Relationship

0
2

Authors

Journals

citations
Cited by 2 publications
(1 citation statement)
references
References 56 publications
0
1
0
Order By: Relevance
“…As mentioned earlier, the synthesis of novel ether-linked perfluorinated polymers was achieved through the NAS mechanism [31]. The polymerization process involved the deprotonation of DAB-A-OH and DAB-Z-OH to generate bis-phenoxide anion (Nu:), followed by the nucleophilic attack of the fluorine positions of the fluorinated linkers such as HFB and DFB.…”
Section: Nucleophilic Aromatic Substitution (Nas) and The Cross-linki...mentioning
confidence: 99%
“…As mentioned earlier, the synthesis of novel ether-linked perfluorinated polymers was achieved through the NAS mechanism [31]. The polymerization process involved the deprotonation of DAB-A-OH and DAB-Z-OH to generate bis-phenoxide anion (Nu:), followed by the nucleophilic attack of the fluorine positions of the fluorinated linkers such as HFB and DFB.…”
Section: Nucleophilic Aromatic Substitution (Nas) and The Cross-linki...mentioning
confidence: 99%