In a general setting of scattering theory, we consider two self-adjoint operators H 0 and H 1 and investigate the behaviour of their wave operators W ± (H 1 , H 0 ) at asymptotic spectral values of H 0 and H 1 . Specifically, we analyse when (W ± (H 1 , H 0 ) − P ac 1 P ac 0 )f (H 0 ) < ∞, where P ac j is the projector onto the subspace of absolutely continuous spectrum of H j , and f is an unbounded function (f -boundedness). We provide sufficient criteria both in the case of trace-class perturbations V = H 1 − H 0 and within the general setting of the smooth method of scattering theory, where the high-energy behaviour of the boundary values of the resolvent of H 0 plays a major role. In particular, we establish f -boundedness for the perturbed polyharmonic operator and for Schrödinger operators with matrix-valued potentials. Applications of these results include the problem of quantum backflow.