In the presence of viscous dissipation and radiation effects, a numerical analysis is performed for an unsteady‐free convective, radiative, chemically reactive, radiation absorption, viscous, incompressible, and electrically conducting fluid passing through an exponentially accelerating vertical porous plate. Numerical methods are used to solve the collection of nondimensional governing equations and their boundary conditions. Graphs are used to study the effects of different physical characteristics on flow quantities. Tables are used to study the differences in skin friction, the Sherwood number, and the Nusselt number for the physical interest. The analysis and explanation of the fluctuation in radiation and flow parameters on velocity and temperature gradient profiles through graphs using the Galerkin technique is the novelty of this work. For the magnetic, Prandtl, heat sink, radiation, Schmidt, and chemical reaction parameters, skin friction is significantly higher; however, for the Grashof, modified Grashof, permeability, radiation absorption, Dufour, and Soret numbers, skin friction has the opposite tendency.