Enhancing combustion efficiency and optimizing the thrust-toweight ratio are critical technical challenges encountered in the development, application, and growth of micro turbojet engines. The high-centrifugal (high-g) combustion chamber, as an innovative combustion chamber system, has the capability to replace the primary combustion chamber of the traditional turbojet engine, reducing the length of the combustion chamber while maintaining engine performance. Previous studies on the structure of the high-g combustor (HGC) have shown problems such as uneven temperature distribution of the turbojet rotor. To improve the feasibility of HGC integration into micro turbojet engines, this study conducts relevant experiments on a 120 N thrust engine. Subsequently, the results of these experiments were used to analyze the structural design of HGC through a simulation approach. Including six main configurations, the first four structural designs focused on establishing a suitable highly centrifugal environment to stabilize and improve the combustion performance, which was successfully achieved by designing the outer ring gearshaped inlet with four different angles. Subsequent structural designs were based around improving the uniformity of the temperature distribution at the combustion chamber outlet. The final design of the HGC combustion efficiency is not much different from the original combustion chamber, and it can shorten the axial length of the combustion chamber by nearly 30%. The design of the air inlet holes and the baffle plate effectively improves the temperature uniformity at the outlet of the combustion chamber. Moreover, without changing the combustion chamber material, the corresponding engine weight can be reduced by about 10.7%, and the engine thrust-to-weight ratio can be improved by up to 12% with the same thrust, which provides design ideas for further lightweight applications.