The
chemical looping process is considered as a suitable way to produce
hydrogen and syngas. CaMnO3, CaFeO3, and CaMn1–x
Fe
x
O3 (x = 0.2 and 0.4) perovskites were prepared
via the sol–gel method. Perovskites were characterized by X-ray
diffraction and thermogravimetry and tested for hydrogen-rich syngas
production from steam gasification of rice husk char in a fixed bed.
The effect of four types of perovskites, temperature (700–900
°C), and steam/char mass ratio (3.6–8.4) on the hydrogen
yield was investigated. The results showed that the H2/CO
ratio order is CaMn0.6Fe0.4O3 >
CaMn0.8Fe0.2O3 > CaFeO3 > CaMnO3 at 750 °C and steam/char mass ratio
of 4.8. The chemical looping steam gasification process of rice husk
char with perovskites was divided into three stages: (a) uncouple
oxygen, (b) catalytic gasification, and (c) partial decomposition.
On the basis of CaMn0.6Fe0.4O3 as
a reaction material, the best operation conditions for the hydrogen-rich
syngas gasification process are 800 °C and steam/char mass ratio
of 7.2. The results also demonstrated that the higher steam/char mass
ratio (8.4) carried out excessive heat based on computational fluid
dynamics simulation. In addition, in comparison to the gasification
reaction with CaMn0.6Fe0.4O3 at the
optimum condition, the yield of CO is higher by the gasification reaction
without CaMn0.6Fe0.4O3. CaMn0.6Fe0.4O3 easily selects catalysis to
CO than H2.