This work presents a study on the additive manufacturing of functionally graded metal-ceramic materials based on Ti64 with boron fibers and particles. For the first time, the phase composition of the obtained composite was investigated using synchrotron radiation. It was shown that during laser exposure and in situ synthesis, boron dissolves in the titanium matrix, forming secondary compounds such as TiB and TiB2. An increase in the microhardness of the formed material compared to the titanium alloy was established. High-speed impact tests on the Ti64-B samples were conducted using an electrodynamic mass accelerator. It was shown that the use of boron fibers in the metallic matrix reduces the depth of the crater created during impact testing by 40% compared to the Ti64 reinforcement-free coating.