The thermal power plants (TPP) make a basis of power-generation industry of the majority of countries. The global growth of power consumption and the policy of energy-saving demand to increase the efficiency of plants operation, which is, among others, determined by the technical level of steam-generating units. The up-to-date digital technologies make it possible to assess the efficiency of boiler furnace operation at the stage of boiler unit designing, its reconstruction or retrofitting and upgrading. Developed in the article are the algorithm, mathematic model and computer program of calculating diffusion-kinetic process of combustion of D-grade Donetsk coal in the coal-dust flame of boiler Е-230-14,0-520. The assigned tasks have been solved by using theoretical methods of analysis, the capabilities of devices of computer-aided calculations have utilized for visualization of results. The considered digital approach to solving technical tasks makes it possible to meet the current and future challenges.