This article aims to study the mass transient diffusion in solids with an arbitrary shape, highlighting boundary condition of the third kind. To this end, the numerical formalism to discretize the transient 3D diffusion equation written in generalized coordinates is presented. For the discretization, it was used the finite volume method with a fully implicit formulation. An application to drying of roof tiles has been done. Three models were used to describe the drying process: (1) the volume V and the effective mass diffusivity D are considered constant for the boundary condition of the first kind; (2) V and D are considered constant for the boundary condition of the third kind and (3) V and D are considered variable for the boundary condition of the third kind. For all models, the convective mass transfer coefficient h was considered constant. The analyses of the results obtained make it possible to affirm that the model 3 describes the drying process better than the other models.
List of symbols
Latin symbols A, BCoefficients of algebraic equation of the discretized equation A 1 , B 1 , C 1 , Constants obtained by non-linear regression for dimensions of the tiles a, bFitting parameters obtained by optimization
D efEffective water diffusivity (m 2 s -1 ) E, L, C Dimensions of the roof tiles (m) hConvective mass transfer coefficient (m s -1 ) J Jacobian of the transformation (m -3 )