Due to the large size of the bottom surface, the slipper pair of the large displacement piston pump (LDPP) will form a larger linear speed difference in the inner and outer positions of the slipper relative to the center of the swash plate during high-speed rotation. It is more likely to lead to the slipper overturning, which makes the slipper partially worn. To make improvements, the comprehensive performance of the slipper pair of the LDPP, the motion law of the slipper pair of the LDPP was explored. Firstly, a mathematical model of the oil film thickness of the slipper pair of the LDPP under the state of residual compression force is established, based on the consideration of the linear velocity difference formed by the high-speed rotation of the large bottom surface slipper and the theory of dynamics and thermodynamics. Secondly, the impact of rotational speed, piston chamber pressure and oil temperature on the oil film thickness of the slipper pair was simulated and analyzed. Finally, to measure the oil film thickness of the slipper pair, oil film thickness measuring equipment was created, and the accuracy of the mathematical model was verified. The study revealed the changing rules of the oil film thickness and tilt angle of the bottom surface of the slipper pair under various working conditions. The consistency of the simulation and test findings demonstrates that the mathematical model can accurately describe influencing elements and changing rules of the LDPP slipper pair’s oil film lubrication characteristics.