In this paper, numerical simulations of single-jet impingement cooling and double-jet impingement cooling processes of heated L-shaped steel are carried out using the VOF model. The SIMPLEC pressure–velocity coupling algorithm and realizable k-ε model are used for the solution. The effects of jet position, water flow, and jet distance in the single-jet condition are analyzed in the simulations. The distributions of impact pressure, turbulence kinetic energy, and Nusselt number were obtained, as well as the variation of the peak values of these three factors with the jet position, water flow, and jet distance. The water flow rate is 3–11 L/min, and the jet distance is 5–25 cm. The effect of the distance between the two nozzles on the jet cooling uniformity under the dual jet condition was also analyzed. The distance between the two nozzles was 15–45 mm. The results showed that the variation of water flow rate had a greater effect on the ability of jet cooling compared with the jet position and jet distance, and the heat transfer efficiency also increased gradually with the increase of water flow, but the increased rate of heat transfer efficiency decreased gradually. When the flow rate increased from 3 to 11 L/min, the maximum instantaneous cooling rates at 1/4 of the thickness of the short side upper side, long side upper side, short side lower side, and long side lower side positions increased by 38.9%, 48.5%, 48.2%, and 32.9%, respectively. To ensure that the jet does not shift, the jet distance should be less than or equal to 10 cm. In the case of the double jet, the nozzle distance is 1.5 cm, and the cooling uniformity of the cooling area between the two nozzles is better. The peak Nusselt number in the cooling area of each part under the double jet cooling condition increased by 5%, 9.4%, 10.2%, and 13.3%, respectively, compared with the single jet.