Within the drilling, petrochemical, construction, and related industries, coatings are used to recover components that failed during service or to prevent potential failures. Due to high stresses, such as wear and corrosion, which the materials are subjected to, industries require the application of coating between dissimilar materials, such as carbon steels and stainless steels, through arc welding processes. In this work, an austenitic stainless steel (ER308) coating was applied to an H13 tool steel substrate using the gas metal arc welding (GMAW) robotic process. The heat input during the process was calculated to establish a relationship between the geometry obtained in the coating and its dilution percentage. Furthermore, the evolution of the microstructure of the coating, interface, and substrate was evaluated using XRD and SEM techniques. Notably, the presence of martensite at the interface was observed. The mechanical behavior of the welded assembly was analyzed through Vickers microhardness, and a pin-on-disk wear test was employed to assess its wear resistance. It was found that the dilution percentage is around 18% at high heat input (0.813 kJ/mm) but decreases to about 14% with reduced heat input. Microhardness tests revealed that at the interface, the maximum value is reached at about 625 HV due to the presence of quenched martensite. Moreover, increasing the heat input favors wear resistance.