Despite the many studies in the last decades, the low-ionization structures (LISs) of planetary nebulae (PNe) still hold several mysteries. Recent imaging surveys have demonstrated that LISs are composed of molecular gas. Here, we report H 2 emission in the LISs of NGC 7009 and NGC 6543 by means of very deep narrow-band H 2 images taken with NIRI@Gemini. The surface brightness of the H 2 1-0 S(1) line is estimated to be (0.46-2.9)×10 −4 erg s −1 cm −2 sr −1 in NGC 7009 and (0.29-0.48)×10 −4 erg s −1 cm −2 sr −1 in NGC 6543, with signal-to-noise ratios of 10-42 and 3-4, respectively. These findings provide further confirmation of hidden H 2 gas in LISs. The emission is discussed in terms of the recent proposed diagnostic diagram R(H 2 )=H 2 1-0 S(1)/H 2 2-1 S(1) versus R(Brγ)=H 2 1-0 S(1)/Brγ, which was suggested to trace the mechanism responsible for the H 2 excitation. Comparing our observations to shock and ultraviolet (UV) molecular excitation models, as well as a number of observations compiled from the literature showed that we cannot conclude for either UV or shocks as the mechanism behind the molecular emission.