The development of
a continuous hydrolysis process of titanium
sulfate is an innovation to the traditional production process of
titanium dioxide by the sulfuric acid process. In the experiment,
a microchannel reactor was designed, and the hydrolysis rate of titanium
sulfate, the particle size, and particle size distribution of metatitanic
acid agglomerates were used as indicators to investigate the effect
of operating conditions on the continuous hydrolysis of titanium sulfate.
The results have shown that as the amount of dilution water increased,
the hydrolysis rate of titanium sulfate decreased, and the particle
size of primary aggregates of metatitanic acid increased from 39 to
54 nm. As the alkali mass concentration of dilution water increased,
the hydrolysis rate of titanyl sulfate increased, and the particle
size of primary aggregates of metastatic acid first decreased and
then increased, and the particle size range was 40–48 nm. As
the flow rate increased, the hydrolysis rate of titanyl sulfate increased,
and the particle size of primary aggregates of metatitanic acid dropped
from 59 to 43 nm. Compared with the batch hydrolysis operation, the
continuous process has stronger anti-disturbance ability, significantly
shorter operation time of the reaction section, and narrower particle
size distribution of the product metatitanic acid.