Digestate represents the semi-liquid byproduct of the anaerobic digestion process. It was estimated that 56 Mtonnes of digestate are annually produced only in Europe. Digestate composition depends on the initial total solids (TS) mixture fed to the digester and by its origin (manure, food wastes, agricultural residues, wastewater sludge). Typical values for the different components include a stabilized organic matter content between 20 and 50 g/L, a good content of nitrogen compounds (2-8 g/kg) and of phosphorous compounds (up to 3 g/kg). In particular, ammonia presence in digestate is interesting for ammonium sulfate production, a fertilizer which favors plants' growth. Traditional ammonium sulfate synthesis is conducted by stripping followed by sulfuric acid absorption, a process which requires high energy and chemicals consumptions. This work investigates the exploitation of solar energy to evaporate the liquid phase of digestate in a lab-scale greenhouse. Digestate vapors, rich in ammonia, are sent in a Drechsler trap, filled with 38% w/w sulfuric acid solution, through three solar air fans. The process has been tested on digestates differing for TS content and origin. It emerged that the process is favored by digestates with high ammonia content, as those originated from manure, and a TS content of about 10% w/w, which allowed to obtain an ammonium sulfate concentration of about 2 M in the final solution.
Statement of NoveltyTraditional ammonium sulfate production from digestate requires a previous solid/liquid separation, further polishing of the liquid phase, followed by stripping and absorption in a sulfuric acid solution. This process is characterized by high energy consumption to heat the digestate and by high reagents consumption. This work proposes an innovative and an environmental sustainable way for the ammonium sulfate recovery from digestate, without a previous solid/ liquid separation. In particular, solar energy is exploited to dry the digestate and to recover ammonia vapors, which are sent to a trap containing H 2 SO 4 to allow the ammonium sulfate production.Publisher's Note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.