Polycrystalline samples with nominal composition of Ba(Fe 1-x Ir x ) 2 As 2 (x=0. 10, 0.15, and 0.20) were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), electrical resistivity, and magnetization measurements. XRD and SEM results showed that almost single phase samples were obtained. Bulk superconductivity with T C~2 8 K was observed in the x=0.10 sample. T C~2 8 K is the highest superconducting critical temperature among the reported data for electron-doped AFe 2 As 2 -type (A=Ca, Sr, and Ba) superconductors. The upper critical field H c2 (0) reaches as high as 65 T for the x=0.10 sample. The underlying physics is discussed in connection with Co-doping case.PACS numbers: 74.70. Dd, 74.25.Fy, 74.62.Dh, 74.62.Bf * Corresponding author. Tel.: +86-10-6251-1523.E-mail address: tszhao@ruc.edu.cn (T.-S. Zhao).-1 -Since the recent discovery of superconductivity in the F-doped RFeAsO (R = La, Ce, Pr, Nd, Sm, and Gd ) and Th-doped GdFeAsO with the highest T C up to as high as 55-56 K [1-6], the FeAs-based superconductors have attracted much attention. Another family of oxygen-free FeAs-based compounds with the ThCr 2 Si 2 -type structure such as K or Na-doped AFe 2 As 2 (A = Ca, Sr, Ba, and Eu) and Co-doped AFe 2 As 2 (A = Sr, Ba) were found to be superconductors with the highest T C up to 38 K [7][8][9][10][11][12][13]. The electron-doped Ba(Fe, Co) 2 As 2 system has been extensively studied and the temperature-composition phase diagram of this system has been determined by several groups [14][15][16][17][18][19][20][21]. The determined phase diagrams show a striking feature that there is a coexistence of antiferromagnetisim and superconductivity in an underdoped region. Very recently, a number of electron-doped Ba (Fe, M) 2 As 2 (M = Ni, Ru, Rh, and Pd) [22][23][24][25] and Sr(Fe, M) 2 As 2 (M = Ni, Ru, Rh, Pd, and Ir) [26][27][28][29] compounds was also found to exhibit superconductivity.Among the electron-doped superconductors, a higher T C was observed in Co-doped BaFe Powder X-ray diffraction (XRD) using Cu K α radiation at room temperature was used to identify phase structure of the samples. Figure 1(a) shows the powder XRD patterns for Table I. It can be seen from Table I that the a-axis increases and the c-axis shrinks slightly with increasing the Ir content x, respectively.We have examined the microstructure and phase composition of the samples using a scanning electron microscope (SEM) (LEO 1450, Carl Zeiss SMT Ltd., Cambridge, UK) equipped with an energy dispersive X-ray (EDX) spectrometer. SEM micrographs show that, comparing with the undoped BaFe 2 As 2 , there is a gradual and considerable decrease in the grain size for the Ir-doped samples with increasing the Ir content. Figures 1(b) and 1(c) show the backscattered electron images for the samples with x = 0.10 and 0.20, respectively. It can be seen that there exists a small fraction of white phase as an impurity phase in the samples. Our EDX analysis shows that the white phase is IrAs 2 phase. In fact, a small pe...