Invoked by the recent CMS observation regarding candidates of the χ b (3P) multiplet, we analyze the ultrafine and mass splittings among 3P multiplet in our unquenched quark model (UQM) studies. The mass difference of χ b2 and χ b1 in 3P multiplet measured by CMS collaboration (10.6±0.64±0.17 MeV) is very close to our theoretical prediction (12 MeV). Our corresponding mass splitting of χ b1 and χ b0 enables us to predict more precisely the mass of χ b0 (3P) to be (10490 ± 3) MeV. Moreover, we predict ratios of the radiative decays of χ bJ (nP) candidates, both in UQM and quark potential model. Our predicted relative branching fraction of χ b0 (3P) → Υ(3S )γ is one order of magnitude smaller than χ b2 (3P), this naturally explains the non-observation of χ b0 (3P) in recent CMS search. We hope these results might provide useful references for forthcoming experimental searches.