In the widely-studied two-color laser scheme for terahertz (THz) radiation from a gas, the frequency ratio of the two lasers is usually fixed at ω2/ω1 =1:2. We investigate THz generation with uncommon frequency ratios. Our experiments show, for the first time, efficient THz generation with new ratios of ω2/ω1 =1:4 and 2:3. We observe that the THz polarization can be adjusted by rotating the longer-wavelength laser polarization and the polarization adjustment becomes inefficient by rotating the other laser polarization; the THz energy shows similar scaling laws with different frequency ratios. These observations are inconsistent with multi-wave mixing theory, but support the gas-ionization model. This study pushes the development of the two-color scheme and provides a new dimension to explore the long-standing problem of the THz generation mechanism.Terahertz (THz) waves have broad applications in THz spectroscopy [1,2] and THz-field matter interactions [3,4]. These applications can potentially benefit from powerful THz radiation sources with various parameters via different laser-plasma-based schemes [5][6][7][8][9]. For example, MV/cm-scale THz radiation with either linear [5,10,11] or elliptical polarization [12][13][14][15] can be generated from gas plasma. THz radiation of near mJ can be produced via relativistic laser interaction with solid plasma [8,[16][17][18]. Among these schemes, the two-color laser scheme [5] has been studied most widely [19][20][21][22][23][24][25][26][27][28] because it can provide high-efficiency tabletop broadband sources. Generally, an 800nm pump laser pulse passes through a frequency-doubling crystal to generate a second-harmonic pulse and then the two pulses are mixed to produce gas plasma. Up to now, the frequency ratio of the two-color pulses has been always taken as ω 2 /ω 1 =1:2 in experiments, although the fundamentalpulse wavelength longer than 800nm was adopted in recent experiments to enhance the THz strength [29][30][31] and the second-harmonic-pulse frequency was detuned to yield ultra-broadband radiation [32]. Since 2013 a few theoretical reports [33][34][35] have predicted that the twocolor scheme could be extended to uncommon frequency ratios such as ω 2 /ω 1 =1:4, 2:3, but these predictions have not yet been verified experimentally.In this Letter, we present the first experimental demonstration of THz generation with uncommon frequency ratios. With the ω 1 -laser wavelength fixed at 800nm and 400nm, respectively, a scan of the ω 2 -laser wavelength from 1200nm to 1600nm shows that the THz energies have three resonantlike peaks located near ω 2 /ω 1 = 1:4, 1:2, and 2:3. The energies at these peaks are at the same order. Beyond the previous predictions [33][34][35], we find that the THz polarization can be adjusted by rotating the ω 2 -pulse polarization and however, the polarization adjustment becomes inefficient by rotating the ω 1 -pulse polarization. In this Letter we define the ω 1 pulse as the higher-frequency one. These observations agree with our particle-in...