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Beyond Ni-Based Superalloys OverviewThis article presents an overview of publications on mechanical properties of chromium and chromium-based alloys, with particular emphasis on ductility at low temperature and strength at high temperature. Analysis of rather scattered data suggests that a chromium or chromium-based alloy can be ductilized at ambient temperature and is quite capable of being strengthened to high levels at high temperature. A new composition design and process would open new opportunities for chromiumbased alloys as structural materials used at temperatures up to 1,300°C.
Beyond Ni-Based Superalloys OverviewThis article presents an overview of publications on mechanical properties of chromium and chromium-based alloys, with particular emphasis on ductility at low temperature and strength at high temperature. Analysis of rather scattered data suggests that a chromium or chromium-based alloy can be ductilized at ambient temperature and is quite capable of being strengthened to high levels at high temperature. A new composition design and process would open new opportunities for chromiumbased alloys as structural materials used at temperatures up to 1,300°C.
The sections in this article are Introduction Oxidation Fundamentals Protective Oxide Scale Formation Reactive Elements Overview Effects on Oxidation Production of Alloys with RE Additions Applicability and Limitations Pesting Ni Al Based Intermetallics Overview Ni Al Transient Oxidation Steady‐State Oxidation Effect of Al Content Alloying Additions Other Corrosive Environments Ni 3 Al Transient Oxidation Steady‐State Oxidation Alloying Effects Fe Al Based Intermetallics Overview Historical Perspective Thermodynamic and Kinetic Considerations in the Fe Al O System Fe 3 Al Fe Al Other Corrosive Environments Sulfur‐Containing Gases Chlorine‐Containing Gases Carbon‐Containing Gases Molten Salts and Condensed Deposits Ti Al Based Intermetallics Overview Ti Al 2 Ti Al 3 τ Phase γ‐ Ti Al Thermodynamic Considerations The Nitrogen Effect Effects of Alloying Additions Engineering Considerations Other Corrosive Environments α 2 ‐ Ti 3 Al and Orthorhombic Ti 2 Al Nb α 2 Alloys Orthorhombic Alloys Nb Al Based Intermetallics Overview Nb Al 3 Nb 2 Al Nb 3 Al Nb Ti Al Precious Metal, Exotic, and Miscellaneous Aluminides Pt Al Intermetallics Ir Al Intermetallics Ru Al Intermetallics Co Al Intermetallics V Al Intermetallics Laves Phases and In‐Situ Composites Overview Single‐Phase Laves Alloys Nb Nb Cr 2 In‐Situ Composites Cr XCr 2 Type In‐Situ Composites Ni Al ‐Based In‐Situ Composites γ‐ Ti Al + Ti ( Cr , Al ) 2 and Nb Al 3 + Nb ( Cr , Al ) 2 In‐Situ Composites Silicides Overview and General Considerations Mo Si 2 Overview High‐Temperature Oxidation Accelerated Oxidation and Pesting Effects of Alloying Additions Composites Other Corrosive Environments Mo 5 Si 3 Ti Si 2 and Ti 5 Si 3 Ti Si 2 Ti 5 Si 3 V 5 Si 3 Cr 3 Si Fe and Ni Silicides Other Silicides Beryllides Overview Complex Beryllides– MBe 13 , MBe 12 , and M 2 Be 17 MBe 2 MBe Phases Acknowledgements
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