Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar. 3. Coumarone-Indene Resins with Methacrylic Fragments

Bratychak, Michael; Astakhova, Olena; Prysiazhnyi, Yuriy; Shved, Mariia; Shyshchak, Olena; Namieśnik, Jacek; Płońska‐Brzezińska, Marta E.; St., Gdansk G. Narutowicza

doi:10.23939/chcht12.03.379

Cited by 10 publications

(4 citation statements)

References 14 publications

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“…with methacrylate fragments. 26 Coumarone-indene resins with methacrylate fragments (CIRM) were obtained by radical cooligomerization of unsaturated hydrocarbons that are part of CCLP (Table 2) and styrene in the presence of 2,2'-azobis(2methylpropionitrile) (AMP) as the initiator (Table 4). To obtain resins with methacrylate fragments, methyl methacrylate (MMA) was added to the mixture.…”

Section: Coumarone-indene Resinsmentioning

confidence: 99%

Resins with Oxygen-Containing Functional Groups Obtained from Products of Fossil Fuels Processing: A Review of Achievements

Prysiazhnyi,

Grynyshyn,

Pyshyev

et al. 2023

ChChT

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To synthesize resins with oxygen-containing functional groups the C9 fractions of hydrocarbon pyrolysis, heavy gasoline, and light coal tar fraction obtained from coal coking liquid products (CCLP) were used. Various types of initiators and industrial monomers were obtained using the above-mentioned non-target and/or by-products of organic raw materials processing: by the initiated oligomerization method (from C9 fractions) – petroleum polymer resins with functional groups; by radical cooligomerization (from CCLP) (with RPKV) – coumarone-indene resins with functional groups. The influence of the main factors controlling the synthesis process of resins with functional groups on their quantitative and qualitative characteristics was studied, including the process temperature, duration, and the reaction mixture composition. The structure of the synthesized resins was analyzed by IR spectroscopy, and the presence of epoxy, carboxyl, hydroxyl, and methacrylate functional groups was confirmed.

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Section: Coumarone-indene Resinsmentioning

confidence: 99%

Resins with Oxygen-Containing Functional Groups Obtained from Products of Fossil Fuels Processing: A Review of Achievements

Prysiazhnyi,

Grynyshyn,

Pyshyev

et al. 2023

ChChT

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“…In particular, the Department of Chemical Technology of Oil and Gas Processing, Lviv Polytechnic National University, is researching the creation and use of various additives and modi ers of road petroleum bitumen derived from liquid products of coking and desulfurization of coal. Resins with different functional groups obtained from non-target or by-products of coal conversion were synthesized and used for this purpose [2,[7][8][9][10][11][12][13][14][15][16][17] or with the addition of low molecular weight organic compounds (formaldehyde and maleic anhydride) [18,19].…”

Section: Introductionmentioning

confidence: 99%

Bitumen Modified with Resins Obtained from Coal Coking Liquid Products: Nature, Adhesive and Rheological Properties

Pyshyev

Prysiazhnyi

Borbeyiyong

et al. 2023

Preprint

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Coumarone-indene (CIR) and coumarone-indene-carbazole resins (CICR) were obtained by ionic cooligomerization based on fractions extracted from liquid products of coal coking (gasoline fractions and coal tar). CIR and CICR are used as road bitumen modifiers to improve thermal resistance and adhesion. A cheap plasticizer has been selected to be used with CIR to produce polymer-modified bitumen (PMB). The change in the composition and properties of bitumen modified with CIR was described. A method for estimating the change in the adhesion properties of bitumen at low temperatures has been developed, which simulates the behavior of bitumen during the operation of pavements in winter and during sharp changes in weather conditions. The possibility of using the obtained CICR as adhesive enhancers for bitumen has been established. It is shown that the addition of these resins significantly increases the adhesion of bitumen to the surface of granite gravel and glass.

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“…4 These byproducts, in particular the light fraction, containing indene, coumarone, styrene and other hydrocarbons. This made it possible to create on its basis the indenecoumarone resins with carboxy, 4 epoxy, 20,21 and methacrylate 22 groups. The synthesized indene-coumarone resins with functional groups are used as active additives to improve the properties of petroleum bitumen.…”

Section: Introductionmentioning

confidence: 99%

Effects of Hydrophilic Silica Nanoparticles on Morphology and Mechanical Properties of a Typical Tyre Compound

Dortaj¹,

Mohebbi²,

Bagheri³

et al. 2022

ChChT

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This research aimed to study the effects of adding hydrophilic silica nanoparticles as nanofiller on tread properties of a typical tyre compound. In this respect, four compounds were prepared as a representative of the tread of the tyre. The amount of 0, 1, 3, and 5 phr (parts of filler per hundred parts of rubber) of nanofiller were added by melt mixing method. Physical and mechanical properties of compounds were measured. The structure and morphology of the fractured surface of the compounds were characterized using field emission scanning electron microscopy (Fe-SEM). The results of cure and mechanical analysis of the compound series showed that the sample containing 3 phr of nanofiller possesses better properties. This observation is due to higher interaction between nanofiller and polymer macromolecules that causes better dispersion of the nanoparticles in polymer matrix.

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Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar. 3. Coumarone-Indene Resins with Methacrylic Fragments

Cited by 10 publications

References 14 publications

Resins with Oxygen-Containing Functional Groups Obtained from Products of Fossil Fuels Processing: A Review of Achievements

Resins with Oxygen-Containing Functional Groups Obtained from Products of Fossil Fuels Processing: A Review of Achievements

Bitumen Modified with Resins Obtained from Coal Coking Liquid Products: Nature, Adhesive and Rheological Properties

Effects of Hydrophilic Silica Nanoparticles on Morphology and Mechanical Properties of a Typical Tyre Compound

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