“…After cooling, the residues of the digestion were diluted with 2 % ultrapure HNO3 to 50 ml PE tubes and stored at 4 °C. The digested steps used in the present study was described by Inal et al (2018) and Benhalima et al (2022), and recommended by the European Centre for Research and Teaching in Environmental Geosciences (CEREGE). Total concentrations of trace metals (Mn, V, Co, Ni, Cr, Cu, Zn, Pb, As, Ag, and Cd) and major elements (Fe, Al and Na) were measured in CEREGE (France) using inductively coupled plasma mass spectrometry (ICP-MS, PerkinElmer NexION 300X, USA) and inductively coupled plasma atomic emission spectrometry (ICP-AES, PerkinElmer Optima 4300 DV, USA), respectively.…”