The characteristics,
distribution, and preservation of pores are
vital in controlling the storage and distribution of shale gas. The
Qiongzhusi Formation shales taken from different members with similar
tectonic and thermal evolutions were used to evaluate the response
of pore characteristics to minerals and sealing systems using field-emission
scanning electron microscopy and gas adsorption. Because of differences
in mineral structure and arrangement, feldspar, organic matter (OM)–clay,
OM–rutile, and OM–apatite aggregates facilitate multiple
types of pores in the shale and influence the relative proportions
of surface porosity for different types of pores owing to differences
in mineral structure and arrangement. Rigid frameworks and pressure
shadows formed by rigid minerals and OM–mineral aggregates
preserved OM and pores to some extent. The sealing capacity of the
floor controls the sealing system and hydrocarbon expulsion efficiency
of the Qiongzhusi Formation in different members. During thermal evolution,
the amount of hydrocarbons generated and expelled affected the stress
equilibrium state between the pore pressure and external stress, influencing
the compaction intensity of shales. The OM pore development characteristics
were evolved with variation in the stress equilibrium state in different
sealing systems. Once the stress equilibrium state was disrupted,
the OM pores deformed, narrowed, or even closed under the influence
of compaction owing to the loss of overpressure support. The pore
characteristics of the Qiongzhusi Formation shales responded significantly
to different sealing systems. A few OM pores are flat and slitlike
in the open system, whereas numerous OM pores are round and elliptical
in the semiopen system. Meanwhile, the average diameter of the OM
pores in the open system was reduced by approximately 40.2% compared
with that of the semiopen system. Furthermore, the pore volume and
specific surface area of the mesopores for open system shales were
reduced by 38.4% and 37.7%, respectively, compared to the semiopen
system. These findings will improve the understanding of the distribution
and preservation of pore in shale and help assess the sweet-spot members
for the Qiongzhusi Formation shale gas.