Octahedral iron(II) complexes with pyridyl triazine and bipyridine ligands – synthesis, computational studies, mechanisms and kinetics with 1,10-phenanthroline and 2,2′,6,2″-terpyridine

Effect of the extended π-surface and N-butyl substituents of imidazoles on their reactivity, electrochemical behaviours and biological interactions of corresponding Pt(ii)-CNC carbene complexes: exploring DFT and docking interactions

“…37,38 Iso-kinetic linear plots of Δ H # versus Δ S # (ESI,† Fig. S17) from a linear free energy relationship (LFER) between the activation parameters further signify that all the reactions follow a similar associatively activated mechanism 39,40 From the plot, the iso-kinetic temperatures and Δ G # for the chloride substitution from PtL 1 –PtL 3 were found to be 294 K and 85 kJ mol −1 , respectively.…”