2018
DOI: 10.3847/1538-4357/aab106
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OH+ Formation in the Low-temperature O+(4S) + H2 Reaction

Abstract: Formation of OH+ in collisions of ground-state O+(4S) ions with normal H2 has been studied using a variable temperature 22-pole RF ion trap. From 300 to 30 K the measured reaction rate coefficient is temperature-independent, with a small decrease toward 15 K. The recent wave packet calculation predicts a slightly steeper temperature dependence. The rate coefficients at 300 and 15 K are almost the same, (1.4 ± 0.3) × 10−9 cm3 s−1 and (1.3 ± 0.3) × 10−9 cm3 s−1, respectively. The influence of traces of the two… Show more

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Cited by 14 publications
(8 citation statements)
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“…Four of our sightlines have data for T 01 (Rachford et al 2002(Rachford et al , 2009Sheffer et al 2008) which range from 59 K for HD 41117 and 101 K for HD 185418, and these correspond to cosmic ray ionization rates which may vary by about a factor of four. Moreover, reactions between molecular hydrogen and O + /OH + have also been recently studied in ion trap experiments at low temperatures (Kovalenko et al 2018;Tran et al 2018). The derived rate coefficients corresponding to k 3 and k 4 are within the same order of magnitude as with previous values, which give differences in the calculated ζ p by at most 20 percent.…”
Section: Discussionsupporting
confidence: 63%
“…Four of our sightlines have data for T 01 (Rachford et al 2002(Rachford et al , 2009Sheffer et al 2008) which range from 59 K for HD 41117 and 101 K for HD 185418, and these correspond to cosmic ray ionization rates which may vary by about a factor of four. Moreover, reactions between molecular hydrogen and O + /OH + have also been recently studied in ion trap experiments at low temperatures (Kovalenko et al 2018;Tran et al 2018). The derived rate coefficients corresponding to k 3 and k 4 are within the same order of magnitude as with previous values, which give differences in the calculated ζ p by at most 20 percent.…”
Section: Discussionsupporting
confidence: 63%
“…More recently, we updated the photorates to those from Heays et al ( 2017) and adopted the exponential integral formalism for the depth dependence due to dust. Additional changes to the chemical rates include oxygen chemistry rates from Kovalenko et al (2018) and Tran et al (2018), and carbon chemistry rates from Dagdigian (2019). In order to compute synthetic line emission intensities we assume a Doppler line width of ∆v = 1.5 km s −1 .…”
Section: Edge-on Pdr Modelsmentioning
confidence: 99%
“…The PDR code used to generate its underlying database of line intensities has improved physics and chemistry. Critical updates include those discussed in Neufeld & Wolfire (2016), plus photorates from Heays et al (2017), oxygen chemistry rates from Kovalenko et al (2018), andTran et al (2018), and carbon chemistry rates from Dagdigian (2019). We have also implemented new collisional excitation rates for [O I] from Lique et al (2018) (and Lique private communication) and have included 13 C chemistry along with the emitted line intensities for [ 13 C II] and 13 CO.…”
Section: Photodissociation Regionsmentioning
confidence: 99%