Comprehensive Organometallic Chemistry III 2007
DOI: 10.1016/b0-08-045047-4/00050-9
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Oligosilanes

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Cited by 11 publications
(9 citation statements)
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“…Since the establishment of Rochow’s direct method in the 1940s, methylchlorosilanes (Me n SiCl 4– n , n = 1–3) have been important feedstocks in the industrial production of silicon-based materials including silicone resins, elastomers, and oils. In addition to these oligomers and polymers, a number of organosilicon compounds have been synthesized from methylchlorosilanes and utilized in organic and inorganic synthesis …”
mentioning
confidence: 99%
“…Since the establishment of Rochow’s direct method in the 1940s, methylchlorosilanes (Me n SiCl 4– n , n = 1–3) have been important feedstocks in the industrial production of silicon-based materials including silicone resins, elastomers, and oils. In addition to these oligomers and polymers, a number of organosilicon compounds have been synthesized from methylchlorosilanes and utilized in organic and inorganic synthesis …”
mentioning
confidence: 99%
“…Furthermore, the H + -forms of these aluminosilicates also contain high contents of tetrahedral Al species, which should be derived from the spiro-7-core structure, and they showed higher activity for the ring-opening reaction of styrene oxide than before the introduction of protons. Therefore, the present method is expected to develop as a promising method for synthesizing new aluminosilicates with a controlled structure, atomic arrangement, and catalytically active sites, inspired by the reported MPs with variable secondary building unit-like structures and Si/Al ratio. …”
Section: Discussionmentioning
confidence: 99%
“…MPs with Si–CR-type leaving groups have been considered as a potential alternative to those with Si–OR-type leaving groups for the construction of aluminosilicates. Si–C bonds are easy to handle and can be activated, they are thermally more active than Si–O bonds, and numerous compounds with Si–C bonds have already been reported. , Among the MPs with Si–CR-type leaving groups, we focused on those with Si–Ph bonds, for which a variety of secondary building unit (SBU)-like MPs have been reported. We have previously demonstrated that a molecule that consists of a tetrahedral Al and six Si atoms with a spiro-7 core supported by 12 Si–Ph bonds, (PyH + )­[Al­{Ph 2 Si­(OSiPh 2 O) 2 } 2 ] − ( PyH + [AlSi 6 ] − ; PyH + = pyridinium cation; Figure ), can be transformed into two zeolites (zeolites L and W) in the presence of KOH under hydrothermal conditions accompanied by base-assisted Si–Ph bond activation . It should be emphasized here that the use of PyH + [AlSi 6 ] − has advantages over synthetic routes that use conventional separate precursors in terms of reproducibility, selectivity, and crystallinity of the two zeolites. On the other hand, the studies also demonstrated that the resulting zeolites L and W possess Si/Al ratios of 1.0–1.2, which are lower than that of PyH + [AlSi 6 ] − ( i .…”
Section: Introductionmentioning
confidence: 99%
“…[88][89][90][91][92] However, silanols are well known for their inherent tendency to self-condensation reactions to form siloxanes. [81,93] This hamper a wider use of trichlorosilanol or trichlorosilyloxide.…”
Section: Group 16mentioning
confidence: 99%