In this paper, local geometrical properties of the velocity and temperature fields of combined forced and natural convection in a vertical slot are studied using large-eddy simulation based on both numerical and analytical approaches. Previous studies on turbulence geometrical statistics appearing in the literature have primarily focused on either isothermal or isotropic turbulent flows; whereas in this work, we extend the scope of research to investigation of a wall-bounded thermal flow. In particular, we focus on studying the resolved helicity, enstrophy generation, local vortex stretching, and a variety of characteristic geometrical alignment patterns between the resolved velocity, vorticity, temperature gradient, subgrid-scale heat flux and the eigenvectors of the resolved strain rate tensor. In order to quantify the effect of buoyancy on the geometrical properties of the thermal flow field, a systematic comparative analysis has been conducted based on three different flow regimes (i.e., viscous sublayer, buffer layer and logarithmic layer) in both the hot and cold wall regions. The near-wall restriction on the geometrical property of the thermal flow field has been analyzed and some interesting wall-limiting geometrical alignment patterns in the form of Dirac delta functions are also reported.