A b-colouring of a graph G is a proper colouring of the vertices of G such that there exists a vertex in each colour class joined to at least one vertex in each other colour classes. The b-chromatic number of a graph G, denoted by φ(G) is the largest integer k such that G has a b-colouring with k colours. The Mycielskian or Mycielski graph µ(H) of a graph H with vertex set {v 1 , v 2 , …, v n } is a graph G obtained from H by adding n + 1 new vertices {u, u 1 , u 2 , …, u n }, joining u to each vertex u i (1 ≤ i ≤ n) and joining u i to each neighbour of v i in H. In this paper, we obtain the b-chromatic number of Mycielskian of paths, complete graphs, complete bipartite graphs and wheels.