“…SMPs find extensive applications in diverse fields including biomedicine, aerospace, textiles, protective equipment, and so on . Furthermore, research has extended into the field of four-dimensional (4D) printing materials, involving the use of biocompatible polycaprolactone softeners to enhance the shape memory effects and FFF printability of poly(vinyl chloride), as well as studies on the applications of polycaprolactone-thermoplastic polyurethane composites. − The most prevalent SMPs among these are heat-triggered SMPs (HSMPs). − The temporary shapes of HSMPs tend to be generated at temperatures higher than the transition temperature ( T trans , glass transition temperature ( T g ) or melting temperature ( T m )), which provides structural flexibility to the chain segments. Shape memory effects (SME) are commonly observed in various block copolymers, where the hard segments possess physical or chemical cross-linked points while the soft segments assume permanent and temporary shapes, respectively.…”