Abstract. We study Pisot numbers β ∈ (1, 2) which are univoque, i.e., such that there exists only one representation of 1 as 1 = n≥1 s n β −n , with s n ∈ {0, 1}. We prove in particular that there exists a smallest univoque Pisot number, which has degree 14. Furthermore we give the smallest limit point of the set of univoque Pisot numbers.