The design of modern multi-detector arrays for Intermediate Energy Nuclear Physics experiments has to face the problem of the improvement of the Charge and Mass Identification of Heavy and Light Charged Products. Most of the detector arrays developed for the identification of mass and atomic number of the emitted fragments, use detection units composed by thin silicon detectors and by thick scintillator crystals read-out by photodiodes. The light output of the CsI(TI) crystal can be modeled -at least in a given energy range -with a combination of two exponential functions with different time constants. The possibility of storing the digitized waveforms allows performing further off-line analyses. In the present work we determine -by direct least-square fitting of the base-line subtracted output waveforms -the four-vector defining the light output ('lj, '1;, hI' hs). In this way it is possible to provide an experimental determination of the scintillator parameters for aManuscript received November 10, 2011. This work was supported by INFN -Istituto Nazionale di Fisica Nucleare in the framework of the EXOCHIM experiment and partly by the MIUR (Ministero dell'Universita' e della Ricerca Scientifica) program PRIN2009 "Studio e realizzazione del prototipo di un sistema di rivelazione ad alta risoluzione angolare per la misura con alta precisione dell'impulso di particelle leggere e di frammenti, da utilizzare per studi di dinamica e spettroscopia in reazioni nucleari con fasci stabili e radioattivi ad energie basse ed intermedie ".A. Castoldi, C. Guazzoni and P. Zambon are with wide energy range and for different particle types. The proposed method has been applied to the waveforms acquired with the CHIMERA 41t detector array during runs at the INFN Laboratori Nazionali del Sud Superconducting Cyclotron in Catania, Italy with different beam/target pairs. In this paper we present the results obtained with a 21.5 MeV/u 2°N e beam bombarding a 12 C target.