This doctorate thesis focuses on the design, fabrication and experimental characterization of novel on-chip spectrometers. Specifically, two different types of on-chip spectrometer have been designed, fabricated and experimentally demonstrated. Fabrication processes based on nano-silicon-photonic (NSP) fabrication technology are developed. The first part of the thesis reports an on-chip spectrometer called predispersed spectrometer with both high resolution and large bandwidth using thermally tunable microring resonator (MRR) array with an arrayed waveguide grating (AWG) before the MRR array. The AWG functions as a fixed filter to predisperse the input spectrum while the following tunable MRRs retrieve the corresponding dispersed spectra with high resolution. By adoption of AWG before the tunable MRR array, the working spectral band can be broadened while maintaining final resolution of the spectrometer due to that the resonance wavelength of MRR can be finely tuned. Besides, the tunable MRR array has much higher fabrication tolerance and is more compact compared to the approaches using the stationary microring resonators array. The pre-dispersed spectrometer achieves high resolution (0.1 nm) and large bandwidth (27 nm) within only 9 channels in a compact size of 3 × 3 mm 2. The model of MRR thermal tuning exploiting thermo-optic (TO) effect is built and theoretically analysed. Heater optimization and thermal isolation trenches are implemented to improve the heating efficiency. The second part of the thesis focuses on the development of a microring resonator-assisted Fourier-transform (RAFT) spectrometer. In this design, Fouriertransform (FT) spectrometer is realized with a thermally tunable photonic Mach-Summary xi Zehnder interferometer (MZI). A microring resonator with high quality factor is cascaded before the Mach-Zehnder interferometer to pre-filter the input spectrum while the MZI is exploited to reconstruct the pre-filtered spectra. The proposed RAFT spectrometer has both high resolution (0.47 nm) and very large bandwidth (90 nm) due to the large transparency widow of Mach-Zehnder interferometer and high quality factor (Q) of microring resonator. It has a small footprint of 2.2 mm 2. The model of MZI thermal tuning exploiting TO effect is built and theoretically analysed. Low-loss Si rib waveguide is designed, fabricated and experimentally tested to reduce insertion loss and improve resolution. A low loss rate of 0.1 dB/m is experimentally tested. Thermal isolation trenches are implemented and experimentally tested to reduce thermal consumption and thermal crosstalk. The third part of the thesis focuses on the development of core fabrication technology of nano-silicon-photonic fabrication technology, including silicon strip waveguide, inverse taper fibre-chip coupler, rib waveguides, directional couplers, and titanium nitride (TiN) heaters and thermal isolation trenches. Si3N4 strip waveguide, microring resonator, and directional coupler are also designed and fabricated. The fabrication processes are deve...