T-stress and mixed-mode stress intensity factors have been determined experimentally using thermoelastic stress analysis and using a finite element method. Pure mode I, strong mixed-mode I and II, and interacting cracks have been used as the case studies. A new technique has been proposed to identify the crack tip from thermoelastic images. It has also been shown that using three terms of Williams's stress field formulation to determine the Tstress, yields a more accurate solution than using only the first two terms of the expansion.