1962
DOI: 10.1085/jgp.45.4.21
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On Dielectric Constant and Enzymatic Kinetics

Abstract: A study was made on the effect of glycine on systems involving trypsin and BAEE 1 or TSAME on the one hand, or a-chymotrypsin with any of the substrates BAEE, TEE, or PEE, on the other. In all cases there was a linear relationship between the rate logarithm and the reciprocal of the dielectric constant of the glycine solution. The slopes were positive in the reactions of trypsin. In those catalyzed by a-chymotrypsin, the slopes were positive at pH 6.5 or lower, and negative at pH 7.5. However, the effects of g… Show more

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1966
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