The backscatter characteristics of ocean surfaces are of great importance in active marine remote-sensing fields. This paper presents the high spatial and temporal resolution dual co-polarized (VV and HH) and cross-polarized (HV) Ka-band sea-surface backscattering measurements taken from the Yellow Sea research platform at incidence angles ranging from 30° to 50° and in the wind speed range from 5.8 to 8.6 m/s. The experimental results show that the backscattering coefficient in HH polarization is close to (or even surpassing) that in VV polarization within a wind speed range of 7.1 to 8.6 m/s for Ka band under high resolution at medium incidence angles (30°–50°). Further analysis of the 10-ms short-time observation samples found that the sea surface echoes in VV polarization are more sensitive to wave motions, exhibiting more complex scattering characteristics such as multi-peaks and reducing scattering energy, especially at high wind speeds and large incident angles. The Doppler velocity analysis also confirms that rapid ocean wave changes can be detected within a short observation period, especially in VV polarization. The research in this article not only demonstrates the high spatial and temporal resolution capabilities of Ka-band radar for ocean surface observation but also reveals its great potential in interpreting and inversing rapidly evolving marine phenomena.