As the boundary conditions of electromagnetic fields and phase matching of electromagnetic waves on interface are the fundamentals to drive the Snell’s laws and Fresnel’s laws, they are also crucial for the propagation analysis of electromagnetic waves in moving medium. There are mainly two methods to derive the boundary conditions of electromagnetic fields on moving interface. One of them is using the kinematic integral form, yet this method is based on the classical time-space. The other is based on the relativistic transformation, the boundary conditions are derived from the scaling effect with geometric method, or from principle of relativity directly. However, the first one obtained a same form as using the kinematic integral form, while the second one got a different one. At the same time, the phase matching of electromagnetic wave on moving interface is only discussed by Galileo transformation, however this is unreasonable, because of the relativistic effect cannot be ignored here. Therefore, it is necessary to reexamine the boundary conditions of electromagnetic fields and phase matching of electromagnetic wave on moving interface. Herein, the relativistic transformation formula of the unit normal vector of moving surface is derived from the surface equation and principle of relativity firstly. Secondly, the boundary conditions of electromagnetic fields on moving interface are given based on the relativistic and non-relativistic transformation formula of the unit normal vector and electromagnetic fields, which show that the boundary conditions of electromagnetic fields on moving interface are in the same form under the relativistic and non-relativistic cases. This is not accidental but determined, because of the change in flux of electromagnetic fields, like in magnetic flux, from the induction of electromagnetic fileds is same to that from the variation of surface element. Thirdly, the phase matching of electromagnetic wave on moving interface are given based on the relativistic transformation formula of the unit normal vector and the phase matching of electromagnetic wave on resting interface. It is easy to get the same results through other methods, applying the phase matching of electromagnetic wave on moving interface in the problem that light is incident on a homogeneous medium which moving with a constant velocity in vacuum or air. The discussion in this article belongs to classical electrodynamic without quantum effects considered, but the results will provide some convenience for the theoretical analysis of electromagnetic communication, remote sensing and telemetering.