Let G be a graph of order n with m edges. Also letbe the largest positive integer such that µ σ ≥ 2m/n. In this paper, we prove that µ 2 (G) ≥ 2m/n for almost all graphs. Moreover, we characterize the extremal graphs for any graphs. Finally, we provide the answer to Problem 3 in [8], that is, the characterization of all graphs with σ = 1.