This paper presents a newly developed high temperature ultrasonic sensor and its application to in-situ observation of aluminum alloy during solidification and melting in temperature up to 800 ºC. The ultrasonic sensor mainly consists of a conventional piezoelectric transducer and a titanium buffer rod as an acoustic waveguide. The length is 300 mm. This sensor, owing to the unique characteristics of titanium, is highly expected to provide not only high acoustic coupling to molten aluminum but also high corrosion resistance. It is demonstrated that the titanium buffer rod has superior sustainability and wettability to the molten aluminum alloy. Using the ultrasonic sensor, the changes of the longitudinal velocity of the aluminum alloy during solidification and melting have been monitored as a function of temperature. Furthermore, a clear reflected echo from the solid-liquid interface of the aluminum alloy has been observed. The movement of the reflected echo due to the growth of the solid-liquid interface has also been monitored during cooling process. Thus, it is demonstrated that the developed ultrasonic sensor using a titanium rod is a promising tool for molten aluminum monitoring.