For the 5D energy-critical wave equation, we construct excited N -solitons with collinear speeds, i.e. solutions u of the equation such thatwhere for n = 1, . . . , N , Qn(t, x) is the Lorentz transform of a non-degenerate and sufficiently decaying excited state, each with different but collinear speeds. The existence proof follows the ideas of Martel-Merle [14] and Côte-Martel [3] developed for the energy-critical wave and nonlinear Klein-Gordon equations.In particular, we rely on an energy method and on a general coercivity property for the linearized operator.