Analogous to the notion of mutually unbiased bases for Hilbert spaces, we consider mutually unbiased unitary bases (MUUB) for the space of operators, M (d, C), acting on such Hilbert spaces. The notion of MUUB reflects the equiprobable guesses of unitary operators in one basis of M (d, C) when estimating a unitary operator in another. Though, for prime dimension d, the maximal number of MUUBs is known to be d 2 − 1, there is no known recipe for constructing them, assuming they exist. However, one can always construct a minimum of three MUUBs, and the maximal number is approached for very large values of d. MUUBs can also exist for some d-dimensional subspace of M (d, C) with the maximal number being d.